There was no immediate comment from police on the identity of the two drivers.
The top speed of a Mercedes E63 AMG is 190mph, and is considered to be the most powerful series-production four door car released by AMG to date.
The drivers of two high performance Mercedes AMG cars have been caught after driving at speeds over 130mph down the A180.
Police have been using an unmarked BMW as part of their operation today.
It has been a busy day for the Humberside Police traffic unit today, seizing three vehicles for driving without any insurance.